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Zircon makes a nice gem but it's out of favor these days.
Zircon-zirconium silicate or ZrSiO4-is a hard stone, ranking 7? on
the Mohs scale, but other stones are harder and its colors aren't
unique. Tradition has a slim dossier on zircon; one site says that
it was reputed to "aid sleep, bring prosperity, and promote honor
and wisdom," but hey, just having the money to own jewels is good
for that. It does have some minor mineralogical distinctions. It's
the only gem in the tetragonal crystal class, for what that is worth.
And it's the densest of the major gemstones, but that means a zircon
of a given carat weight is smaller than any other gem of equal weight.
Maybe zircon can gain more respect if we look at its value to
geologists. Zircon grains occur almost everywhere there are
sediments, because the mineral is so tough. It rises through
the crust in igneous rocks and is eroded into the stream system,
washed out to sea, and laid down in the sediment beds where it
becomes part of the next cycle of sandstone and shale-totally
unaffected! Zircon is the ultimate geological recyclable; it can
even endure metamorphism. That makes it a great indicator mineral.
If you find it in a granite in one place, and in a sandstone
somewhere else, you have learned something about the geologic
history and geographic setting that brought the zircons from the
first to the second place.
The other thing about zircon is its impurities, especially uranium.
The uranium-lead (U-Pb) system of dating rocks has been refined to
great accuracy, and U-Pb zircon dating is now a precise tool for
rocks as old as Earth itself, some 4.6 billion years. Zircon is good
for this because it holds these elements tightly.
Cubic zirconia or CZ is known as a fake diamond, but I think it
should instead be considered a superior zircon. CZ is a manufactured
oxide compound, ZrO2, not a silicate, and "zirconia" is a chemical
name, not a mineral name.
There is a naturally occurring form of zirconia, called baddeleyite.
The difference between baddeleyite and CZ is the way the zirconium
and oxygen atoms are packed: the mineral is a monoclinic crystal and
the gem is cubic (isometric), the same crystal structure as diamond.
That makes CZ extremely hard-only diamond, sapphire, and chrysoberyl
can scratch it.
The United States stockpiles over 14,000 tonnes of baddeleyite for its
zirconium content. Like zircon it is useful for dating extremely old
rocks, though unlike zircon its use is limited to igneous rocks.
Zirconolite, CaZrTi2O7, is neither a silicate nor an oxide but rather
a titanate. In 2004 it was reported to be even better for dating old
rocks than zircon, yielding data as precise as the SHRIMP (sensitive
high-resolution ion microprobe) instrument allows. Zirconolite,
though rare, may be widespread in igneous rocks but not recognized
because it resembles rutile. The way to identify it for sure is by
using specialized electron microscopy techniques on the tiny grains
before deploying the SHRIMP on them. But these techniques can derive
a date from a grain only 10 microns wide.
The Geologist's Gem
To get an idea of what people can do with zircons, consider what
researcher Larry Heaman did, as reported in the April 1997 Geology.
Heaman extracted zircon (and baddeleyite) from a set of ancient
Canadian dikes, getting less than a milligram from 49 kilograms of
rock. From these specks, less than 40 microns long, he derived a
U-Pb age for the dike swarm of 2.4458 billion years (plus or minus
a couple million), just after the close of the Archean Eon in
earliest Proterozoic time.
From that evidence he reassembled two big chunks of ancient North
America, tucking the "Wyoming" terrane underneath the "Superior"
terrane, then joined them to "Karelia," the terrane underlying
Finland and adjacent Russia. He called his results evidence of
the world's earliest episode of flood-bastitle volcanism or Large
Igneous Province (LIP).
Heaman capped himself by speculating that the first LIP "could
reflect either (1) the waning of a vigorous mantle convection
regime that prevailed during the Archean and completely dissipated
mantle plumes for more than half of Earth's history, or (2) the
time of catastrophic collapse of a stable density stratification
in the Earth's core that led to a sudden increase in heat flux at
the core-mantle boundary." This is a lot to get out of a few tiny
bits of zircon and baddeleyite.